Khamrang et al.: 1,4-Dimethylpiperazine-2,3-dione #CrystalStructure #HalfChair #HydrogenBonding #IUCr https://journals.iucr.org/paper?S2414314624009362
In the title compound, C6H10N2O2, the piperazine-2,3-dione ring adopts a half-chair conformation. In the crystal, the molecules are linked by weak C—H⋯O hydrogen bonds, forming (010) sheets.
Marmande et al.: N,N′-Dibenzylethylenediammonium dichloride #CrystalStructure #SideReaction #HydrogenBonding #IUCr https://journals.iucr.org/paper?S205698902400954X
Modulation of the phenyl groups in N,N′-dibenzylethylenediammonium dichloride in P21/n allows for the formation of a network of strong N—H⋯Cl hydrogen bonds and C—H⋯Cl interactions and breaks C2/c symmetry.
Vassilyeva et al.: Triclinic polymorph of bis[2-methyl-3-(pyridin-2-yl)imidazo[1,5-a]pyridin-2-ium] tetrachloridocadmium(II) #CrystalStructure #CdII #OrganicinorganicHybrid #IUCr https://journals.iucr.org/paper?S2056989024009654
The photoluminescent properties of the monoclinic and triclinic polymorphs in the solid state are strictly comparable, presumably because the spatial organization of both polymorphs is quite similar.
Blockhaus and Sünkel: Molecular and crystal structures of six poly(arylsulfinyl)- and poly(arylsulfanyl)ferrocenes #CrystalStructure #Sulfanylferrocene #Sulfinylferrocene #IUCr https://journals.iucr.org/paper?S2053229624009318
The structures of four polysulfinyl- and two polysulfanylferrocenes were examined. Nonclassical C—H⋯X (X = O, S and C) hydrogen bonds have a large influence on most of the individual crystal structures, with different importance for the sulfinyl and sulfanyl compounds. Chalcogen O⋯O, S⋯S or S⋯O bonding is not significant, except for one compound, and π–ring interactions are important for only one compound.
Uppu et al.: Structure of 2,3,5-triphenyltetrazol-3-ium chloride hemipentahydrate #CrystalStructure #RedoxIndicator #CellularRespiration #IUCr https://journals.iucr.org/paper?S205698902400940X
The packing of the title hydrated molecular salt features an unusual O—H⋯π interaction.
Reynolds et al.: Crystal structure and Hirshfeld surface analysis of {2-[bis(pyridin-2-ylmethyl)amino]ethane-1-thiolato}chloridocadmium(II) #CrystalStructure #HirshfeldSurfaceAnalysis #ChelatingNSLigands #IUCr https://journals.iucr.org/paper?S2056989024009198
A mononuclear cadmium(II) complex [CdLCl], where HL = 2-[bis(pyridin-2-ylmethyl)amino]ethane-1-thiol, was synthesized and characterized by single-crystal X-ray diffraction and Hirshfeld analysis.
Benlatreche et al.: Crystal structure and Hirshfeld surface analysis of trichlorido(1,10-phenanthroline-κ2N,N′)phenyltin(IV) #CrystalStructure #HirshfeldSurfaceAnalysis #CHClHydrogenBond #IUCr https://journals.iucr.org/paper?S2056989024009150
The title compound, which was obtained by the reaction between 1,10-phenanthroline and phenyltin trichloride in methanol, exhibits intramolecular interactions involving the chlorine and hydrogen atoms. Crystal cohesion is ensured by intermolecular C—H⋯Cl hydrogen bonds, as well as Y—X⋯π and π-stacking interactions
Moroni et al.: Synthesis, crystal structure and Hirshfeld surface analysis of sulfamethoxazolium methylsulfate monohydrate #CrystalStructure #HydrogenBonding #MethylSulfate #IUCr https://journals.iucr.org/paper?S2056989024009204
The title molecular salt was prepared by the reaction of sulfamethoxazole and H2SO4 in methanol and crystallized from methanol–ether–water. Protonation takes place at the nitrogen atom of the primary amino group. In the crystal, N—H⋯O hydrogen bonds (water and methylsulfate anion) and intermolecular N—H⋯N interactions involving the sulfonamide and isoxazole nitrogen atoms, link the components into a tri-dimensional network, which also features face-to-face π–π interactions between the phenyl rings of adjacent molecules.
Nazarov et al.: 8-Hydroxyquinolinium trichlorido(pyridine-2,6-dicarboxylic acid-κ3O,N,O′)copper(II) dihydrate #Pyridine26DicarboxylicAcid #Hydroxyquinoline #CrystalStructure #IUCr https://journals.iucr.org/paper?S2056989024009186
The title compound, (C9H8NO)[CuCl3(C7H5NO4)]·2H2O, was synthesized by reacting CuII acetate, 8-hydroxyquinoline, and pyridine-2,6-dicarboxylic acid in dilute hydrochloric acid in a 1:1:1 molar ratio. The Cu(II) atom exhibits a distorted octahedral geometry coordinated by the H2pydc ligand and chloride atoms. In the crystal structure, various hydrogen bonds and weak interactions lead to the formation of a three-dimensional network.