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Structural Chemistry
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Acta Crystallographica Section C, an IUCr journal, reports exciting science with structural content and important results relating to the chemical sciences. journals.iucr.org/c/
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Schlachta et al.: Formation of a di­iron–(μ-η1:η1-CN) com­plex from aceto­nitrile solution #OrganometallicIronIIComplex #AcetonitrileCleavage #NHeterocyclicCarbene #IUCr https://journals.iucr.org/paper?S2053229624007058

Formation of a di­iron–(μ-η1:η1-CN) com­plex from aceto­nitrile solution
Formation of a di­iron–(μ-η1:η1-CN) com­plex from aceto­nitrile solution

A di­iron end-on μ2-η1:η1-CN-bridged com­plex is obtained from a crystallization experiment of an open-chain iron–NHC com­plex. The cyanide appears to originate from the aceto­nitrile (MeCN) solvent by C—C bond cleavage or through carbon–hy­dro­gen oxidation.

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SC
Structural Chemistry
@actacrystc.bsky.social
Acta Crystallographica Section C, an IUCr journal, reports exciting science with structural content and important results relating to the chemical sciences. journals.iucr.org/c/
16 followers9 following54 posts
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