If anyone knows of anything I've missed here, feel free to drop a comment. Innovations in superhero iconography can be difficult to trace due to the often incremental nature of changes and the sheer volume of material involved.

Pursuit, Chapter 2: An uncharacteristically aggressive Spider-Man pumps hoods for info. Mary Jane confronts Peter about his increasingly obsessive behavior. Meanwhile, a disguised Chameleon hires a hi-tech merc known as Tracer to distract Spider-Man while he plots his endgame.